TABLE OF CONTENTS |
February 2017 Volume 16, Issue 2 |
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| Editorial News and Views Perspective Reviews Letters Articles Corrigendum
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Focus | Top |
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2D materials beyond graphene | | | Transition metal dichalcogenides and Xenes have been recently added to the family of 2D materials. This Focus issue highlights the intriguing fundamental properties that these 2D materials and their combination in van der Waals heterostructures exhibit, as well as potential applications.
2D materials beyond graphene |
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Editorial | Top |
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As thin as it gets p155 doi:10.1038/nmat4854 As the family of 2D materials expands to include transition metal dichalcogenides and Xenes, novel fundamental properties and applications come to light.
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News and Views | Top |
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Perspective | Top |
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Buckled two-dimensional Xene sheets pp163 - 169 Alessandro Molle, Joshua Goldberger, Michel Houssa, Yong Xu, Shou-Cheng Zhang et al. doi:10.1038/nmat4802 The current state-of-the-art and possible future developments on two-dimensional silicene, germanene, and stanene sheets (called 2D-Xenes), and their ligand-functionalized derivatives (Xanes), are discussed.
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Reviews | Top |
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Mixed-dimensional van der Waals heterostructures pp170 - 181 Deep Jariwala, Tobin J. Marks and Mark C. Hersam doi:10.1038/nmat4703 This Review discusses the different, state-of-the-art applications of heterostructures containing at least one layer of a two-dimensional (2D) material, combined with 0D, 1D and 3D nano-objects.
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Polaritons in layered two-dimensional materials pp182 - 194 Tony Low, Andrey Chaves, Joshua D. Caldwell, Anshuman Kumar, Nicholas X. Fang et al. doi:10.1038/nmat4792 This Review discusses the properties of polariton modes (plasmon, phonon and exciton) in graphene, hexagonal boron nitride and transition metal dichalcogenides for applications across the terahertz to visible spectrum.
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Letters | Top |
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Superconducting exchange coupling between ferromagnets pp195 - 199 Yi Zhu, Avradeep Pal, Mark G. Blamire and Zoe H. Barber doi:10.1038/nmat4753 The superconductivity is found to control the magnetic configuration in GdN/Nb/GdN spin valves as a result of an antiferromagnetic exchange interaction arising from the coupling between the superconducting condensation energy and the magnetic state.
See also: News and Views by Golubov & Kupriyanov |
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A charge density wave-like instability in a doped spin-orbit-assisted weak Mott insulator pp200 - 203 H. Chu, L. Zhao, A. de la Torre, T. Hogan, S. D. Wilson et al. doi:10.1038/nmat4836 TSr3Ir2O7 is shown to realize a weak Mott state with no cuprate analogue and to exhibit, when electron doped, a charge density wave-like Fermi surface instability with unconventional and possibly short-ranged nature.
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Thermoelectric detection and imaging of propagating graphene plasmons pp204 - 207 Mark B. Lundeberg, Yuanda Gao, Achim Woessner, Cheng Tan, Pablo Alonso-González et al. doi:10.1038/nmat4755 A device is presented that can detect mid-infrared plasmons in graphene encapsulated by hexagonal boron nitride via the thermoelectric effect; the natural decay product of the plasmons (electronic heat) is converted into a measurable voltage signal.
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Observation and coherent control of interface-induced electronic resonances in a field-effect transistor pp208 - 213 J. O. Tenorio-Pearl, E. D. Herbschleb, S. Fleming, C. Creatore, S. Oda et al. doi:10.1038/nmat4754 The electrical control and readout of single two-level state defects in a defective oxide film grown directly on the channel of a thin-film FET allow for the extraction of individual long relaxation times.
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Quasicrystalline nanocrystal superlattice with partial matching rules pp214 - 219 Xingchen Ye, Jun Chen, M. Eric Irrgang, Michael Engel, Angang Dong et al. doi:10.1038/nmat4759 The complex 3D structure of a quasicrystalline binary nanocrystal superlattice has been resolved by electron microscopy and tomography.
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Conductive MOF electrodes for stable supercapacitors with high areal capacitance pp220 - 224 Dennis Sheberla, John C. Bachman, Joseph S. Elias, Cheng-Jun Sun, Yang Shao-Horn et al. doi:10.1038/nmat4766 Using MOFs as active electrodes in electrochemical double layer capacitors has so far proved difficult. An electrically conductive MOF used as an electrode is now shown to exhibit electrochemical performance similar to most carbon-based materials.
See also: News and Views by Vlad & Balducci |
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Understanding trends in C–H bond activation in heterogeneous catalysis pp225 - 229 Allegra A. Latimer, Ambarish R. Kulkarni, Hassan Aljama, Joseph H. Montoya, Jong Suk Yoo et al. doi:10.1038/nmat4760 A universal descriptor for the prediction of C–H bond activation barriers has been established, and combined with a thermodynamic analysis of methane activation, to provide design rules for various types of heterogeneous catalysts.
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Single-platelet nanomechanics measured by high-throughput cytometry pp230 - 235 David R. Myers, Yongzhi Qiu, Meredith E. Fay, Michael Tennenbaum, Daniel Chester et al. doi:10.1038/nmat4772 A high-throughput hydrogel-based platelet-contraction cytometer is able to quantify single-platelet contraction forces and may function as a clinical diagnostic biophysical biomarker.
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Deterministic encapsulation of single cells in thin tunable microgels for niche modelling and therapeutic delivery pp236 - 243 Angelo S. Mao, Jae-Won Shin, Stefanie Utech, Huanan Wang, Oktay Uzun et al. doi:10.1038/nmat4781 Single cells encapsulated in a layer of alginate and injected intravenously delay clearance kinetics and sustain donor-derived soluble factors in vivo.
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Articles | Top |
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High-resolution three-dimensional structural microscopy by single-angle Bragg ptychography pp244 - 251 S. O. Hruszkewycz, M. Allain, M. V. Holt, C. E. Murray, J. R. Holt et al. doi:10.1038/nmat4798 The 3D structure of a diffracting volume can be reconstructed from a set of 2D coherent Bragg diffraction patterns. The overdetermination afforded by ptychography allows the deconvolution of the third dimension, without having to rotate the sample.
See also: News and Views by Robinson & Huang |
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Charge-transport model for conducting polymers pp252 - 257 Stephen Dongmin Kang and G. Jeffrey Snyder doi:10.1038/nmat4784 A generalized charge-transport model is reported that is able to describe the thermopower–conductivity relation at various temperatures in several semiconducting polymers, suggesting a rethinking of conduction mechanisms in these materials.
See also: News and Views by Urban |
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Hybrid organic–inorganic inks flatten the energy landscape in colloidal quantum dot solids pp258 - 263 Mengxia Liu, Oleksandr Voznyy, Randy Sabatini, F. Pelayo García de Arquer, Rahim Munir et al. doi:10.1038/nmat4800 An improved ligand-exchange process allows the realization of solution-deposited films of quantum dots with reduced energetic disorder and, as a result, solar cells with improved open-circuit voltage, charge-carrier transport and stability.
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Nitroaromatic detection and infrared communication from wild-type plants using plant nanobionics pp264 - 272 Min Hao Wong, Juan P. Giraldo, Seon-Yeong Kwak, Volodymyr B. Koman, Rosalie Sinclair et al. doi:10.1038/nmat4771 Plants can be engineered to serve as self-powered pre-concentrators and autosamplers of analytes in ambient groundwater and as infrared communication platforms that can send information to a smartphone.
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Corrigendum | Top |
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Corrigendum: Real-space imaging of interfacial water with submolecular resolution p273 Jing Guo, Xiangzhi Meng, Ji Chen, Jinbo Peng, Jiming Sheng et al. doi:10.1038/nmat4844
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