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| You will need these materials. |
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| Dissolve 3 tablespoons of copper sulfate in 2 cups of warm water. |
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| Place the stickers on the hinge and submerge in the solution for 30 minutes. |
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| Put on some gloves, remove the hinge and clean with toothpaste and a cloth. |
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| Dip the hinge in the solution again, this time for one minute. Remove and allow to dry. |
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| You now have your own copper-plated ornament! |
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Try this: Electro-ornament
Safety: This activity involves chemicals. See the CSIRO Education safety page for more information.
You will need
- Copper sulfate, available from gardening stores
- Zinc-plated hinge
- Water
- Jar
- Star stickers
- Latex gloves
- Measuring spoon
- Measuring cup
- Cloth
- Toothpaste
What to do
- Place 3 tablespoons of copper sulfate into the jar. Add 2 cups of warm water to the jar and stir until it dissolves.
- Place a few stickers onto the zinc-plated hinge.
- Submerge the hinge in the copper sulfate solution for 30 minutes.
- Put on a pair of rubber gloves and remove the hinge from the solution. Rinse it with water.
- Using the cloth and a small amount of toothpaste, polish the surface of the metal until it is clean. Be careful not to remove the stickers. Rinse the hinge with water.
- Dip the hinge back into the solution for one minute. Remove it from the solution and rinse it with water. Allow the hinge to dry.
- Remove the stickers. You now have your own copper-plated ornament!
What's happening?
In this activity there are many metals to consider: steel (which is mostly made of iron), zinc and copper. The hinge is made of steel and covered in a thin layer of zinc. At the start of the activity, there isn't any copper metal but there are blue copper ions in the solution.
Some metals lose their surrounding electrons more easily than others. Of the three metals involved in this activity, zinc loses its electrons most easily, followed by steel then copper.
When the hinge is dipped in the solution, the zinc loses its electrons which react with the copper ions in solution. The products of this reaction are zinc ions and copper metal, which plates out on the hinge. The reaction can be represented as follows:
Zn(s) → Zn2+(aq) + 2e-
Cu2+(aq) + 2e- → Cu(s)
When you remove and clean the hinge, the copper layer comes away quite easily, leaving the steel exposed. The second time you dip the hinge in the solution, a similar reaction occurs, although this time it is the iron in the steel which forms ions.
The first reaction happens slower than the second. This is because zinc is a passivating metal. This means the zinc reacts with oxygen in the air to form a layer of zinc oxide which protects the metal beneath. It takes time for the copper ions to work their way through to react with the zinc. While the more reactive zinc is present, the copper ions will react with it instead of the iron.
When you remove the outer layer between the dips, you remove the protective zinc coating. In the second dip, the copper ions will react with the exposed steel leaving a shiny, copper coating.
Applications
These reactions are examples of redox reactions. Redox reactions have important applications, a major one being batteries. Batteries use different metals and an electrolyte to produce electrical energy.
Plating one metal with another is a common procedure. Examples include chrome plating of steels in cars; zinc plating of screws, nuts and bolts; and gold plating of jewellery.
More information
By Patrick Mahony
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